Octadecabromidobis(dicarbido)decadysprosium, [Dy10Br18(C2)2]
نویسندگان
چکیده
Single crystals of [Dy(10)Br(18)(C(2))(2)] were obtained during the reaction of DyBr(3) with dysprosium metal and graphite in a sealed tantalum container. In the crystal structure, the Dy atoms form dimers of edge-sharing octa-hedra, each encapsulating a C(2) unit. The metal atoms are surrounded by Br atoms above the cluster edges and vertices, respectively. The dimers are connected to each other by Br atoms, leading to a three-dimensional network. [Dy(10)Br(18)(C(2))(2)] is isotypic with its iodido analogue [Dy(10)I(18)(C(2))(2)].
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007